Product ID:PHILLYBOND #6 RESIN, 3210R, PART A
MSDS Date:09/10/1998
FSC:1015
NIIN:01-198-7563
Kit Part:Y
MSDS Number: CKJHY

Emergency Phone: 800-424-9300

Info Phone: 215-855-8450

Cage: 0SFY9

Telephone: 215-855-8450

Cage: 0SFY9

CRYSTALLINE SILICA

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

BISPHENOL A DIGLYCIDYL RESIN (DGEBPA)

CAS: 25068-38-6

RTECS: CE6880000

LD50 LC50 Mixture:LD50 (ORAL,RAT): 11,400 MG/KG
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: MODERATE IRRITANT.
CONTACT AT ELEVATED TEMPERATURES CAN CAUSE THERMAL BURNS. MAY CAUSE
SKIN SENSITIZATION (RASHES, HIVES). EYES: MODERATE IRRITANT.
CONTACT AT ELEVATED TEMPERATURES CAN CA USE THERMAL BURNS.
INHALATION: LOW VAPOR PRESSURE OF RESIN MAKES INHALATION UNLIKELY
IN NORMAL USE. INGESTION: ACUTE ORAL TOXICITY IS LOW. MAY CAUSE
GASTRIC DISTRESS. CHRONIC: PROLONGED OR REPEATED SK IN CONTACT MAY
CAUSE SENSITIZATION, WITH ITCHING, SWELLING, OR RASHES ON LATER
EXPOSURE. THIS PRODUCT IS PART A OF A TWO-PART KIT; HANDLE
FRESHLY-MIXED RESIN AND HARDENER AS RECOMMENDED FOR HARDENER.
AFTER CURING, PRODUCT IS NOT HAZARDOUS.
Explanation of Carcinogenicity:MANUFACTURERS MSDS STATES IN RESPECT TO
CARCINOGENICITY, "NOT REGULATED BY OSHA, ACGIH, NTP, OR IARC"; ALSO
STATES "CONTAINS NO CANCER-SUSPECT CONSTUTENTS. SEE TOXICOLOGICAL
INFORMATION FIELD FOR ADDI TIONAL INFORMATION IN RESPECT TO PRODUCT
CARCINOGENICITY.
Effects of Overexposure:EYES: IRRITATION, THERMAL BURNS. SKIN:
IRRITATION, THERMAL BURNS, SKIN SENSITIZATION, RASHES, HIVES,
ITCHING, SWELLING. INHALATION: NOT LIKELY TO OCCUR. INGESTION:
ACUTE ORAL TOXICITY IS LOW. MAY CAUS E GASTRIC DISTRESS.
Medical Cond Aggravated by Exposure:PREEXISTING EYE AND SKIN DISORDERS.
DEVELOPMENT OF PREEXISTING SKIN OR LUNG ALLERGY SYMPTOMS MAY
INCREASE.

First Aid:EYES: FLUSH WITH CLEAN WATER FOR AT LEAST 15 MINUTES WHILE
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE
CONTAMINATED CLOTHING AND EXCESS CONTAMINANT. FLUSH SKIN WITH
WATER. WASH WITH SOA P AND WARM WATER. CONSULT A PHYSICIAN IF
IRRITATION DEVELOPS. INHALATION: MOVE TO FRESH AIR. ADMINISTER
OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION IF
SYMPTOMS PERSIST. INGESTION: DO NOT INDUCE VOMIT. GIVE 2 GLASSES
OF WATER TO DILUTE IF PATIENT IS CONSCIOUS. GET MEDICAL ATTENTION.
NOTE TO PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN
HIGH VISCOSITY, LOW VOLATILITY PRODUCT S, E.G., EPOXY RESINS.

Flash Point Method:PMCC
Flash Point:>204.4C, 400.F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:MATERIAL WILL NOT BURN UNLESS PREHEATED. DO
NOT ENTER CONFINED SPACE W/OUT FULL BUNKER GEAR. FIREFIGHTERS
SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE
CLOTHING COOL FIRE EXPOSED CONT AINERS WITH WATER.
Unusual Fire/Explosion Hazard:HEATING ABOVE 300 F IN PRESENCE OF AIR
MAY CAUSE SLOW OXIDATIVE DECOMPOSITION AND ABOVE 500 F MAY CAUSE
POLYMERIZATION. WHEN HEATED TO DECOMPOSITION IT EMITS FUMES OF
CHLORINE, CARBON MONOXIDE, OTHE R FUMES AND VAPORS VARYING IN
COMPOSITION AND TOXICITY.

Spill Release Procedures:AVOID CONTACT. ELIMINATE IGNITION SOURCES.
VENTILATE AREA. DIKE AND ABSORB WITH CLAY, SAND, OR OTHER SUITABLE
MATERIAL. PREVENT SPILL FROM ENTERING DRAINAGE/SEWER SYSTEM,
WATERWAYS,SURFACE WATERS. PUM P LARGE SPILLS TO STORAGE/SALVAGE
VESSELS. SOAK UP RESIDUE WITH ABSORBENT SUCH AS CLAY, SAND/OTHER
SUITABLE MATERIAL AND DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO
REMOVE TRACE RESIDUE.

Handling and Storage Precautions:STORE IN COOL, DRY AREA AWAY FROM HIGH
TEMPERATURES AND FLAMES. AVOID CONTACT WITH SKIN, EYES, CLOTHING.
WASH THOROUGHLY WITH SOAP AND WATER AFTER USING AND PARTICULARLY
BEFORE EATING, DRINKING, SMOKI NG, OR USING TOILET FACILITIES.
LAUNDER CONTAMINATED CLOTHING AND PROTECTIVE GEAR BEFORE REUSE.
Other Precautions:DISCARD CONTAMINATED LEATHER ARTICLES. HANDLE MIXED
RESIN AND HARDENER I/A/W POTENTIAL HAZARD OF CURING AGENT USED.
PROVIDE ADEQUATE VENTILATION/REPIRATORY PROTECTION AGAINST
DECOMPOSITION PRODUCT S DURING WELDING/FLAME CUTTING OPERATIONS AND
TO PROTECT AGAINST NUISANCE DUST DURING SANDING/GRINDI NG OF CURED
PRODUCT.

Respiratory Protection:NONE REQUIRED AT NORMAL HANDLING TEMPERATURES
AND CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGES FOR
UNCURED RESIN AND NIOSH APPROVED DUST/PARTICLE RESPIRATORS DURING
GRINDING/SANDING OPERAT IONS OF CURED RESIN AS EXPOSURE LEVELS
DICTATE.
Ventilation:LOCAL EXHAUST VENTILATION IS PREFERRED, GOOD GENERAL
MECHANICAL VENTILATION IS USUALLY ADEQUAT FOR MOST APPLICATIONS.
USE LOCAL EXHAUST FOR CONFINED AREAS.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment:HAVE EMERGENCY SHOWER AND EYE WASH
AVAILABLE. WEAR OTHER GEAR AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY WITH SOAP AND WATER AFTER USING
AND PARTICULARLY BEFORE EATING, DRINKING, SMOKING, APPLYING
COSMETICS, OR USING TOILET FACILITIES.
Supplemental Safety and Health
MANUFACURERS MSDS STATES, IN RESPECT TO CARCINOGENICITY, "NOT REGULATED
BY OSHA, ACGIH, NTP, OR IARC; ALSO "CONTAINS NO CANCER-SUSPECT
CONSTITUENTS". SEE TOXICOLOGICAL INFORMATION FIELD FOR ADDITIONA L
INFORMATION IN RESPECT TO CARCINOGENICITY. THIS NSN
1015-01-198-7563 WAS CANCELLED WITHOUT REPLACEMENT, JUNE 1, 1992.

HCC:V5
Boiling Pt:>260.C, 500.F
Vapor Pres:0.03 @ 171F
Vapor Density:>1(AIR=1)
Spec Gravity:1.81
pH:NEUTRAL
Evaporation Rate & Reference:<1, (BUTYL ACETATE =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:OFF WHITE PASTE WITH LITTLE ODOR.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS, STRONG MINERAL
AND ORGANIC BASES (ESPECIALLY PRIMARY AND SECONDARY ALIPHATIC
AMINES).
Stability Condition to Avoid:OPEN FLAME AND EXTREME HEAT.
Hazardous Decomposition Products:OXIDES OF CARBON; ALDEHYDES, ACIDS AND
OTHER ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION OR
ELEVATED TEMPERATURE (>500 DEG F) DEGRADATION.
Conditions to Avoid Polymerization:HEAT GENERATED WHEN RESIN MIXED WITH
CURING AGENTS. RUN-A-WAY REACTION MAY DECOMPOSE RESIN,GENERATING
UNIDENTIFIEDTOXIC FUMES

Waste Disposal Methods:IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). DISPOSE OF ACCORDING
TO APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.

Toxicological Information:LD50(RAT),ORAL= 11,400 MG/KG. ORAL
LD50(MOUSE)=15.6 G/KG. ACUTE INHALATION: LC50(RAT): NO DEATHS IN
SATURATE IN 8 HRS. SUBCHRONIC: NO DATA AVAILABLE. ACUTE DERMAL
EFFECTS: LD50(RABBIT):>20 ML/KG. EYE IRRITATION: NO DATA. CHRONIC
EFFECTS: 2-YR BIOASSAYS IN MICE EXPOSED BY DERMAL ROUTE TO EPON
828, DGEBPA/OTHER COMMERCIAL RESINS YIELDED LIMITED EVIDENCE OF
WEAK CARCINOGENICITY. AUTHORS CONCLUDED THA T RENAL TUMOR EVIDENCE
WITH EPON 828 "WAS OF NO BIOLOGICAL SIGNIFICANCE" AND THAT RESIN
"IS NOT A SYSTEMIC CARCINOGEN WHEN APPLIED TO DORSAL SKIN OF CF1
MICE". (SEE "OTHER INFORMATION" FIELD).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: NO DATA AVAILABLE. MOBILITY AND PERSISTENCE: NO
DATA AVAILABLE. ENVIRONMENTAL FATE: NO DATA AVAILABLE.

Transport Information:PROPER SHIPPING NAME: NON-REGULATED. HAZARD
CLASS: N/A.

SARA Title III Information:CLASSIFICATION OF THIS MATERIAL FOR SARA
SECTION 312 HAZARDOUS MATERIALS INVENTORY REPORTING: IMMEDIATE
HEALTH HAZARD. DELAYED HEALTH HAZARD.
Federal Regulatory Information:TSCA: ALL INGREDIENTS OF PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON TSCA INVENTORY. EXPORT
NOTIFICATION IS REQUIRD UNDER TSCA SECTION 12B. THE FOLLOWING RCRA
CODE APPLIES TO THIS MATERIAL IF I T BECOMES WASTE: NONE.
REGULATORY STATUSOF HAZARDOUS CHEMICAL CONSTITUENTS OF THIS
PRODUCT: CRYSTALLINE SILICA, NOT EXTREMELY HAZARDOUS, NO TOXIC
CHEMICAL. NO CERCLA RQ(LBS). NO TSCA 12B EXPORT NOTIF ICATION
REQUIRED. BISPHENOL A DIGLYCIDYL ETHER RESIN, NOT EXTREMELY
HAZARDOUS, NO TOXIC CHEMICAL, NO , CERCLA RQ(LBS), REQUIRED TSCA
12B EXPORT NOTIFICATION.
State Regulatory Information:CLASSIFICATION OF THIS MATERIAL FOR SARA
SECTION 312 HAZARDOUS MATERIALS INVENTORY REPORTING: IMMEDIATE
HEALTH HAZARD. DELAYED HEALTH HAZARD. CANADIAN REGULATIONS. WHMIS
HAZARD CLASS(ES): D2B. ALL COM PONENT OF THIS PROD ARE ON THE
DOMESTIC SUBSTANCES LIST. HAZARDOUS MATERIALS INFORMATION SYSTEM
(HMIS) RATINGS: HEALTH 2, FLAMMABILITY 1, REACTIVITY 1. CANADIAN
REGULATIONS: WHIMIS HAZARD CLASS(ES): D 2B. ALL COMPONENTS OF THIS
PRODUCT ARE ON THE DOMESTIC SUBSTANCES LIST. OTHER INFORMATION:
HAZARDOUS MATERIALS INFORMATION SYSTEM (HMIS) RATINGS: HEALTH= 2;
FLAMMABILITY= 1; REACTIVITY= 1.